Effect of Damage Processes on Spallation Life in Thermal Barrier Coatings

Abstract

Thermal barrier coatings (TBCs) provide thermal insulation to high temperature superalloys. TBCs consist of an outer ceramic layer that provides good thermal insulation due to the low thermal conductivity of the ceramic used, and the inner metallic bond coat layer that provides needed oxidation resistance to the underlying superalloy. The microstructure of the bond coat changed from high aluminum concentration beta-(Ni, Pt)3Al phase, which has a very good oxidation resistance, to beta-(Ni, Pt)3Al plus gamma'-(Ni, Pt)3Al dual phase microstructure due to oxidation and interdiffusion between the bond coat and the substrate during the thermal test in air. The microstructure change influenced the oxidation behaviors of the bond coat. Less protective oxide (Ni-rich) formed on gamma-(Ni, Pt)3Al due to depletion of aluminum, and the oxide scale on gamma'-(Ni. Pt)3Al ha less adhesion to the bond coat. The TGO Layer and bond coat was subjected to high residual radial stresses during cool down from oxidation temperature du to the thermal expansion mismatch between the different layers. The high residual stress initiated the damages in TGO layer, the TBC/TGO interface and the TGO/bond coal interface as well. The evolution of the damages in TBCs resulted in local loss in adhesion of the coating during thermal cycling. The formation and evolution of micro-decohesion was the key failure mechanism of TBC for lone term thermal cycling. Thermal wave imaging technique as non-destructive and non-contact method was successfully used to monitor the health of TBC. The results reveal that there was no major delamination in TBC specimens during thermal tests.

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Document Details

Document Type
Technical Report
Publication Date
Nov 09, 2001
Accession Number
ADA397661

Entities

People

  • Golam Newaz

Organizations

  • Wayne State University

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical

DTIC Thesaurus Topics

  • Adhesion
  • Alloys
  • Barrier Coatings
  • Chemistry
  • Coatings
  • Failure Mode And Effect Analysis
  • Heat Energy
  • Materials
  • Materials Engineering
  • Materials Science
  • Mechanical Working
  • Mechanics
  • Oxidation Resistance
  • Phase Transformations
  • Substrates
  • Thermal Conductivity
  • Three Dimensional

Fields of Study

  • Materials science

Readers

  • Fire Suppression Systems Design.
  • Structural Health Monitoring of Composite Structures.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics