Excimer Laser Fragmentation-Fluorescence Measurements of Acetylene to Advance Fundamental Understanding of Soot Formation

Abstract

An excimer laser was purchased to perform in-situ measurements of acetylene in fuel-rich flames. The acetylene measurements were performed by fragmenting acetylene with the intense 193 nm wavelength laser output and then detecting the fluorescence from CH and C2 fragments that were formed in excited states. The measurements were compared with mass spectrometer measurements and were shown to agree spatially. The data were used to determine where a soot model accurately predicted the spatial distribution of hydrocarbon growth regions in flames and the trends followed by the peak acetylene concentrations in response to changes in combustion conditions.

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Document Details

Document Type
Technical Report
Publication Date
Nov 13, 2001
Accession Number
ADA397746

Entities

People

  • Charles Mcenally
  • Lisa Pfefferle

Organizations

  • Yale University

Tags

Communities of Interest

  • C4I
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aromatic Hydrocarbons
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Climate Change
  • Combustion
  • Cyclic Hydrocarbons
  • Detection
  • Dye Lasers
  • Excimer Lasers
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Lasers
  • Mass Spectrometers
  • Measurement
  • Spatial Distribution
  • Spectrometers

Readers

  • Combustion science or combustion engineering.
  • Computational Modeling and Simulation
  • Nanofabrication and Microfabrication.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers