Interdiffusion of HgTe/CdTe Hetero-Interfaces

Abstract

In this paper results are presented from a study of interdiffusion in HgTe/CdTe heterostructures. The samples were grown by MBE at HRL Laboratories and had Cd x values ranging from 0.2 to 0.35. The samples were annealed at temperatures ranging from 250 deg C to 425 deg C in both Hg vapor and vacuum ambients. The samples annealed under vacuum were coated with a layer of CdTe prior to annealing. The data were simulated using Darken's equation, and results show strong agreement between the simulated and experimental profiles. Significantly more diffusion was observed for anneals under Hg-rich ambients than under vacuum. For Hg-rich anneals, the activation energy was 1.50 eV at temperatures less than 350 deg C and 1.33 eV at higher temperatures. This is the first time that two activation energies for the interdiffusion coefficient have been reported. The mechanisms responsible for this behavior are discussed.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1998
Accession Number
ADA400077

Entities

People

  • H. G. Robinson
  • J. L. Johnson
  • K. Kosai
  • S. L. Gleixner
  • W. J. Hamilton

Organizations

  • SRI International

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Annealing
  • Band Gaps
  • Chemistry
  • Coefficients
  • Detectors
  • Diffusion
  • Diffusion Coefficient
  • Electrons
  • Energy
  • Equations
  • Experimental Data
  • Fermi Levels
  • Heat Of Activation
  • Low Temperature
  • Point Defects
  • Simulations
  • Simulators

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology