Enzymatic Degradation of HD

Abstract

An enzyme, derived from a Rhodococcus bacterium, was found to have catalytic activity with HD as the substrate. The enzyme has previously been characterized as a hydrolytic dehalogenase and apparently catalyzes the hydrolysis reaction of HD, because chloride is released stoichiometically. The enzyme is precipitated between 60 and 100% ammonium sulfate saturation, binds to Q Sepharose and elutes at an ammonium sulfate concentration of about 0.1%. The enzyme exhibits saturation kinetics with HD as its substrate. The Km is about 15 mM HD and the V(sub max) occurs at about 25 mM. It exhibits fairly conventional temperature and pH effects with a temperature optimum of about 35 deg C and a pH optimum of about 7.0.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 2001
Accession Number
ADA400437

Entities

People

  • Steven P. Harvey

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Human Systems

DTIC Thesaurus Topics

  • Bacteria
  • Chemical Compounds
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Chlorides
  • Degradation
  • Enzymes
  • Escherichia Coli
  • Hydrolysis
  • Kinetics
  • Materials
  • Nerve Agents
  • Polysaccharides
  • Saturation
  • Substrates
  • Technical Information Centers

Fields of Study

  • Biology

Readers

  • Analytical Chemistry
  • Mathematics or Statistics
  • Molecular and Cellular Biochemistry