A Multi-Tracer Push-Pull Diagnostic Test for Assessing the Contributions of Volatilization and Biodegradation During In Situ Air Sparging

Abstract

This paper describes the development and application of a diagnostic tool for local measurements of mass transfer during operation of an IAS system. The diagnostic test involves injecting a solution containing multile tracer compounds through a monitoring well, piezometer, or drive point into the target treatment zone. The injected solution is initially deoxygenated and can contain: (a) a non-degradable, non-volatile conservative tracer, (b) one or more non-degradable, volatile chemicals, and (c) a biologically degradable, non-volatile compound. After a predetermined hold time, an excess quantity of groundwater is extracted from the same injection point and then changes in the concentrations of the tracer compounds are measured. Volatilization and oxygen consumption rates are then estimated from mass balances on the tracer components. This approach is different from other IAS monitoring options in that the measurements can be made without requiring pre-IAS data and results and can be obtained relatively quickly. Furthermore, in principle, the approach is capable of assessing both the rate of oxygen transfer to the aquifer and the rate of volatilization from the aquifer.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 2001
Accession Number
ADA406046

Entities

People

  • Cristin L. Bruce
  • Illa L. Amerson-treat
  • Paul C. Johnson
  • Richard L. Johnson

Organizations

  • Battelle Memorial Institute

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Biodegradation
  • Data Reduction
  • Detectors
  • Ecology
  • Engineering
  • Environmental Pollutants
  • Field Tests
  • Groundwater
  • Mass Transfer
  • Measurement
  • Monitoring
  • Petroleum
  • Petroleum Industry
  • Pull Tests
  • Rate Of Consumption
  • Test Methods

Readers

  • Computational Modeling and Simulation
  • Groundwater Contamination Remediation.