Temperature Dependence of the Cl + HN(3) Reaction from 300 to 480 K

Abstract

The rate constant for Cl + HN3 over the temperature range 300 - 480 K has been studied in a flow reactor. Based on the rate of loss of HN3 and the rate of NCl(a) generation, the temperature dependence of this reaction is described by the collision theory expression 1.2 +/- 0.3 x 10(exp -11) T(sup 0.5) exp(-1514 +/- 93/T), with E(sub o) = 3.0 +/- 0.2 kcal/mol or an Arrhenius fit kappa(T) = 2.0 +/- 1.0 x 10(exp -10) exp(-1452 +/- 150/T) with E(sub a) = 2.9 +/- 0.2 kcal/mol.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1999
Accession Number
ADA406412

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  • Gerald C. Manke Ii
  • Gordon D. Hager
  • Thomas L. Henshaw
  • Timothy J. Madden

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  • Air Force Research Laboratory

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