Membrane-Based Fuel Deoxygenation for Coke Suppression

Abstract

A prototype membrane module for on-line removal of dissolved oxygen, that would otherwise react to form coke precursors, was constructed and successfully demonstrated. Fuel flows over the polymer membrane, while oxygen diffuses through it at a rate that is proportional to the difference in oxygen partial pressures across the surface. Tests were conducted with membranes of different thickness, and over a range of fuel flow rates (residence times) and temperatures. The membrane was shown to be capable of removing essentially all of the dissolved oxygen (to <1 ppm). Fuel deoxygenation proved to be very effective in suppressing autoxidative coke formation, making it possible to increase the maximum allowable temperature and more than double the available heat sink. Moreover, deoxygenated Jet A was shown to perform as well as JP-7, the Air Force's highest thermal stability fuel. An analytical model for oxygen permeation through the membrane was formulated, and used in conjunction with the test data to show that practical size (i.e., low-volume/high-flow rate) deoxygenators can be designed for use in aircraft 5 systems.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 2002
Accession Number
ADA406601

Entities

People

  • Louis J. Spadaccini
  • Steven H. Huang

Organizations

  • United Technologies Corporation

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Aircrafts
  • Deoxygenation
  • Diffusion Coefficient
  • Efficiency
  • Flow Rate
  • Fuel Systems
  • Gas Turbines
  • Heat Sinks
  • Jet Engine Fuels
  • Mass Transfer
  • Partial Pressure
  • Thermal Stability
  • Thickness
  • Turbines
  • Walls

Readers

  • Fluid Dynamics.
  • Petroleum Engineering
  • Underwater engineering and Marine Technology.