Synthesis of Acetogenin Analogs as Potential Therapeutics for Treating Prostate Cancer

Abstract

Toward the objective of creating new acetogenin analogs as potential therapeutics for treating prostate cancer, all of the key substructures and building blocks have been prepared, and assembling them into the first analogs has commenced. All synthetic challenges encountered during the project thus far have been successfully overcome, and work is proceeding as planned. As an additional bonus from this work, a new cobalt complex was developed that catalyzes the stereoselective oxidative cyclization of bis-homoallylic alcohols to trans-tetrahydrofurans in high yield. This new catalyst is likely to see wide spread use in medicinal chemistry.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2002
Accession Number
ADA407206

Entities

People

  • Brian L. Pagenkopf

Organizations

  • University of Texas at Austin

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Alkenes
  • Alkynes
  • Catalytic Oxidation
  • Chemical Synthesis
  • Chemistry
  • Materials
  • Neoplasms
  • Organic Chemistry
  • Organosilicon Compounds
  • Prostate
  • Prostate Cancer
  • Thin Films

Fields of Study

  • Chemistry

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