Tritylsulfinylamine: A New Member in the Family of Sulfinylamines

Abstract

Triphenylmethyl N-sulfinylamine (trityl-NSO) was prepared from the reaction of trityl amine and SOCl2. Trityl-NSO was characterized by 1H, 13C, and 14N NMR spectroscopy in CH2C12 solution and by Raman and infrared spectroscopy in the solid state. Crystals of trityl NSO were grown from n-heptane and characterized by single crystal X-ray diffraction (P1-bar, alpha = 8.9642(9) A, b = 9.2135(9) A, c = 11.0645(11) A, alpha = 93.578(2)0, Beta = 101.098(2)0, gamma = 118.1420, Z = 2, and R(sub int) = 0.0332 at 223 K). Trityl-NSO represents the first alkyl N-sulfinylamine that has been fully structurally characterized.

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Document Details

Document Type
Technical Report
Publication Date
Sep 25, 2002
Accession Number
ADA407891

Entities

People

  • Karl O. Christe
  • Michael Gerken
  • Ralf Haiges
  • Stefan Schneider
  • Thorsten Schroer

Organizations

  • University of Southern California

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Alkanes
  • Charge Coupled Devices
  • Chemistry
  • Crystal Lattices
  • Crystals
  • Diffraction
  • Diffractometers
  • Materials
  • Raman Spectra
  • Single Crystals
  • Spectra
  • Spectroscopy
  • Vibrational Spectra
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Analytical Mechanics
  • Materials Science and Engineering.
  • Organic Chemistry