Reaction of CH2 with O-Atoms: A Source for CO-Chemiluminescence

Abstract

The interactions of carbonaceous combustion species in rocket plumes with the atmosphere are thought to play an important role in the production of ultraviolet, visible, and infrared radiation signatures at high altitudes. A detailed understanding of the pertinent chemical reactions that produce the electronically excited species, and of the competing quenching reactions that remove the internal energy in radiation-less processes is needed to accurately calculate plume spectral signatures and absolute radiances (in the short wavelength region), and their temporal/spatial evolution in the high atmosphere. To facilitate these efforts, we are currently carrying Out laboratory investigations to elucidate the reaction mechanism(s) in the oxidation of CH, CH2, C2H, and C2O with O-atoms and O2.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Apr 13, 2001
Accession Number
ADA409989

Entities

People

  • Ghanshyam L Vaghjiani

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Air Force
  • Air Force Research Laboratories
  • Atmospheres
  • Chemical Kinetics
  • Chemical Reactions
  • Chemiluminescence
  • Data Rights
  • Department Of Defense
  • Dynamics
  • High Altitude
  • Infrared Radiation
  • Military Research
  • Molecular Dynamics
  • Radiation
  • Reaction Mechanisms
  • Short Wavelengths

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Organic Chemistry
  • Spectroscopy.

Technology Areas

  • Microelectronics