Development of Laulimalide-Based Microtubule-Stabilzing Agents: New Chemistry for the Treatment of Breast Cancer

Abstract

Through a collaborative research program involving Utah State University and the Cancer Research Center of Hawaii, we have discovered that the sponge-derived macrolides laulimalide and isolaulimalide are potent cytotoxins with paclitaxel-like antimicrotubule stabilizing activity. Laulimalide is a potent inhibitor of cellular proliferation with an IC50 in the low nanomolar range and it maintains activity against a drug resistant, P-glycoprotein over-expressing ovarian cancer cell line. Laulimalide represents a lead compound for new class of microtubule-stabilizing agents with activities that may prove therapeutically useful for the treatment of breast cancer. The aim of this project is to utilize a combinatorial solid-phase synthetic approach for the construction of a library of laulimalide analogs for structure activity relationship (SAR) studies. In an effort to discover a new chemotherapeutic agent for the treatment of breast cancer we propose to do the following: I) transfer our current solution-phase synthetic approach to solid phase, 2) using a split and pool strategy, prepare 260 laulimalide analogs, 3) test laulimalide analogs for microtubule-stabilizing activity, cytotoxicity against both drug-sensitive and drug-resistant breast cell lines, and 4) submit active analogs to the NCI for screening in the 60-cell line.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2002
Accession Number
ADA410243

Entities

People

  • Bradley S. Davidson

Organizations

  • Utah State University

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Alcohols
  • Biochemistry
  • Biomedical Research
  • Breast Cancer
  • Cancer
  • Cell Line
  • Cells
  • Chemical Synthesis
  • Chemistry
  • Chemotherapeutic Agents
  • Cytoskeleton
  • Materials
  • Neoplasms
  • Oxidation
  • Solid Phases
  • Sulfur Compounds

Fields of Study

  • Chemistry

Readers

  • Clinical Trial Research.
  • Molecular and Cellular Biochemistry
  • Oncology (Cancer Research).