Silicon Etching in LAPPS

Abstract

Initial tests using LAPPS to etch silicon with sulfur hexafluoride-containing plasmas were carried out. Material removal rates and anisotropy were determined with respect to gas composition and substrate RF-induced self-bias level. At room temperature, the removal rate increased linearly with substrate bias. Mixtures of argon and sulfur hexalluoride etched approximately ten times faster (5000 A/min) than similar mixtures of oxygenisulfur hexalluoride (^500 A/min), with the difference being attributed to the passivation of the silicon by involatile silicon oxyfluoride (SiO(x)F(y),) compounds. At low-incident ion energies, these involatile species are believed to cause the observed tapered feature profiles, which became more vertical with increasing ion energy. Plasma and surface chemistry are also discussed, including the negative ion character of these plasmas.

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Document Details

Document Type
Technical Report
Publication Date
Mar 14, 2003
Accession Number
ADA412285

Entities

People

  • D. D. Blackwell
  • D. Leonhardt
  • Richard F. Fernsler
  • Robert A. Meger
  • Scott G. Walton

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Charge Carriers
  • Chemical Reactions
  • Chemistry
  • Dissociation
  • Electron Beams
  • Electrons
  • Energy
  • Films
  • Gas Ionization
  • Ionization
  • Magnetic Fields
  • Materials
  • Measurement
  • Microelectromechanical Systems
  • Physics
  • Radio Frequency Power
  • Surface Chemistry

Fields of Study

  • Materials science

Readers

  • Nanofabrication and Microfabrication.
  • Organic Chemistry
  • Pulsed Power and Plasma Physics.