Synthesis and Characterization of the trans-IO2F5(2-) Dianion

Abstract

The combination of CH3CN solutions of N(CH3)4F and a mixture of cis- and trans-N(CH3)4IO2F4 produces the novel trans-IO2F5(2-) anion. Under the given conditions, only the trans-IO2F4(-) anion acts as a fluoride ion acceptor, thus allowing the separation of isomerically pure, soluble cis-IO2F4(-) from insoluble trans-IO2F5(2-).

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Document Details

Document Type
Technical Report
Publication Date
Feb 11, 2003
Accession Number
ADA412563

Entities

People

  • David A. Dixon
  • Jerry A. Boatz
  • Karl O. Christe
  • Michel Gerken
  • William J. Casteel Jr.

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Chemistry
  • Electron Diffraction
  • Energy
  • Fluorine
  • Frequency
  • Ion Lasers
  • Low Temperature
  • Materials
  • Melting Point
  • Military Research
  • Raman Spectra
  • Raman Spectroscopy
  • Spectra
  • Spectroscopy
  • Vibrational Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology