Organic-Inorganic Interactions in Hydrothermal Processing
Abstract
The effect of inorganic species alone and on organic reactions at hydrothermal conditions was being investigated. The method involves the use of real-time IR spectroscopy in a windowed flow reactor. The specific studies were directed at the water gas shift reaction below the critical temperature of water; the kinetics of decomposition of nickel tetracarbonyl, sodium tetracarbonylcobaltate, and cyclopentadienyl cobalt dicarbonyl at hydrothermal conditions; decarboxylation and defluorination of trifluoroacetate and fluoroform; and the decomposition of an organoazide and sodium azide at hydrothermal conditions.
Document Details
- Document Type
- Technical Report
- Publication Date
- Oct 26, 2002
- Accession Number
- ADA412728
Entities
People
- Thomas B. Brill
Organizations
- University of Delaware