Surface Cracking and Interface Reaction Associated Delamination Failure of Thermal and Environmental Barrier Coatings

Abstract

In this paper, surface cracking and interface reactions of a BSAS coating and a multi-layer ZrO2-8wt%Y2O3 and mullite/BSAS/Si thermal and environmental barrier coating system on SiC/SiC ceramic matrix composites were characterized after long-term combined laser thermal gradient and furnace cyclic tests in a water vapor containing environment. The surface cracking was analyzed based on the coating thermal gradient sintering behavior and thermal expansion mismatch stress characteristics under the thermal cyclic conditions. The interface reactions, which were largely enhanced by the coating surface cracking in the water vapor environment, were investigated in detail, and the reaction phases were identified for the coating system after the long-term exposure. The accelerated coating delamination failure was attributed to the increased delamination driving force under the thermal gradient cyclic loading and the reduced interface adhesion due to the detrimental interface reactions.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 2003
Accession Number
ADA413960

Entities

People

  • Dongming Zhu
  • Jeffrey I. Eldridge
  • Kang N. Lee
  • Robert A. Miller
  • Sung R. Choi

Organizations

  • National Aeronautics and Space Administration

Tags

Communities of Interest

  • Space

DTIC Thesaurus Topics

  • Barrier Coatings
  • Ceramic Coatings
  • Ceramic Matrix Composites
  • Chemical Reactions
  • Coatings
  • Composite Materials
  • Cyclic Tests
  • Delamination
  • Environment
  • Heat Flux
  • Military Research
  • Sintering
  • Space Sciences
  • Thermal Expansion
  • Turbines
  • Vapors
  • Water Vapor

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Reinforced Composite Materials
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Directed Energy