Geochemistry of Hydrothermal Vent Fluids from the Northern Juan de Fuca Ridge

Abstract

To rigorously constrain the role of organic compounds in crustal alteration processes at mid-ocean ridges, quantitative information on the abundances and distributions of organic compounds in hydrothermal vent fluids is required. This thesis was undertaken to provide this information for several low-molecular weight organic compounds (C(1)-C(4) alkanes, C(2)-C(3) alkenes, benzene and toluene) in fluids collected in July, 2000, at three sites on the northern Juan de Fuca Ridge: the Dead Dog and ODP Mound fields, which are located at Middle Valley, and the Main Endeavour Field (MEF), located on the Endeavour segment. The relative abundances of alkane-alkene pairs were used to constrain subsurface reaction zone temperatures. Isotopic systematics of CO2, C(1)-C(4) alkanes, and benzene provided information on the residence times of fluids in the subsurface and the reaction mechanisms that control the distributions of aqueous organic compounds. The presence of organic compounds in these fluids also controlled the distributions of inorganic compounds-most notably, H(2). Integration of the data on both organic and inorganic species in these fluids provides a powerful tool to befter constraining models of subsurface conditions in hydrothennal vent environments.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 2003
Accession Number
ADA415906

Entities

People

  • Anna M. Cruse

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • C4I
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Computer Programs
  • Geochemistry
  • Geology
  • Inorganic Chemicals
  • Inorganic Chemistry
  • Isotopes
  • Mineralogy
  • Organic Chemistry
  • Ridges
  • Seabed
  • Tectosilicates

Fields of Study

  • Environmental science

Readers

  • Oceanography.
  • Organic Chemistry
  • Systems Analysis and Design