Control of Semiconductor Epitaxy by Application of an External Field

Abstract

With the growing demand for reduction in size of semiconductor devices, understanding the chemistry and physics at the atomistic level is becoming an essential part of the design of devices based on electronic materials. One of the major challenges in this area is to obtain desired surface morphology of a thin film by controlling external parameters, such as temperature and pressure. The smoothness of a thin-film surface depends on the rate of surface diffusion of the adatoms during the growth process. Enhancing surface diffusion can lead to a smooth film. In other words, the rate of surface diffusion will depend on how strongly the adatoms bind to the surface. Reducing the binding energy of the adatoms with the surface will result in enhanced surface diffusion. In the present work, the authors show how application of an external field can be used to control binding energy. First-principle calculations were performed to calculate binding energies at different field strengths and orientations, followed by Kinetic Lattice Monte Carlo simulations to obtain surface microstructure. Using the above methods, the authors established a correlation between the external field (strength and orientation) and the microstructure of GaN thin film in MBE process. They have shown that by controlling the strength and orientation of the external field one can obtain GaN thin film with the desired roughness. (25 figures, 9 refs.)

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Document Details

Document Type
Technical Report
Publication Date
Jun 11, 2003
Accession Number
ADA416353

Entities

People

  • Debasis Sengupta
  • Dimitris Pavlidis

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chemistry
  • Compound Semiconductors
  • Electronic Materials
  • Epitaxial Growth
  • First Principles Calculations
  • Materials
  • Materials Science
  • Monte Carlo Method
  • Quantum Chemistry
  • Semiconductor Devices
  • Semiconductors
  • Simulations
  • Solid State Electronics
  • Thin Films
  • Three Dimensional
  • Two Dimensional

Fields of Study

  • Materials science

Readers

  • Economics
  • Quantum Chemistry
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene