Polynitrogen Chemistry. Preparation and Characterization of (N5)2SnF6,N5SnF5, and N5B(CF3)4
Abstract
The successful synthesis of the 2:1 salt (N5+)2SnF6(2-) demonstrates that compounds with touching polynitrogen cations can be prepared, and that the synthesis of an ionic, all nitrogen compound is in principal possible. This paper also shows that N5+ salts, other than N5SbF6 and N5AsF6, can be prepared by metathetical reactions. This method was applied to the syntheses of N5B(CF3)4, N5+SnF(5), and (N5(+))2SnF6(2-).
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 21, 2003
- Accession Number
- ADA416766
Entities
People
- Ashwani Vij
- Eduard Bernhardt
- Karl O. Christe
- Vandana Vij
- William W. Wilson