Signal Transduction by Designed Metal-Binding Proteins

Abstract

The objective of this research is to develop designed metal-binding proteins to report upon the presence of metal ions in solution. We use small, robust protein frameworks as scaffolds on which to design novel metal-ion binding sites. The metal binding site design is computational, to allow an exhaustive sampling of all possible sites. The sites are designed with defined geometries and a variety of primary ligands to metal, which allow a range of different metal-ion binding specificities and affinities to be arrayed. The aim is to couple the metal-binding event to a change in fluorescence of an appropriate probe. For practical applications, reagent-less systems are preferred, but in the development stages, extrinsic reporter probes are also investigated.

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Document Details

Document Type
Technical Report
Publication Date
Aug 05, 2003
Accession Number
ADA416956

Entities

People

  • Lynne Regan

Organizations

  • Yale University

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Biochemistry
  • Carrier Proteins
  • Cell Physiological Processes
  • Chemistry
  • Classification
  • Fiber-Optic Cables
  • Fluorescence
  • Geometry
  • Immobilized Proteins
  • Military Research
  • New York
  • Proteins
  • Sampling
  • Security
  • Universities

Fields of Study

  • Chemistry

Readers

  • Computational Modeling and Simulation
  • Electrochemical Surface Science
  • Molecular and Cellular Biochemistry