Capacity Trends in Nickel Electrodes as Affected by Temperature and Electrolyte Concentration

Abstract

An extensive review of the capacity trends of six representative nickel electrodes has been completed. The nickel electrodes were either taken from cells that had been successfully cycled for 40,000 simulated low Earth orbit cycles or were very new in terms of their life cycle history. One type of testing carried out on these electrodes determined their flooded capacity at four different temperatures under two different charging regimes when using two different electrolyte concentrations. The other type of testing determined the positions of the different charging peaks relative to the potential at which the co-evolution of oxygen becomes a significant factor during the charging process. The results of this study have explained why the use of certain temperatures and electrolyte concentrations can result in desirable or undesirable cell performance characteristics. The reasons behind two of the characteristic lower cell capacity phenomenon related to the use of 26% KOH vs. 31% KOH as the cell electrolyte concentration have become evident based on the results of this study.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 2002
Accession Number
ADA417267

Entities

People

  • Albert H. Zimmerman
  • G. A. To
  • L. H. Thaller

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Advanced Electronics
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Beta Testing
  • Chemical Reactions
  • Chemistry
  • Compound Semiconductors
  • Cycles
  • Detectors
  • Electrodes
  • Electrolytes
  • Fluid Mechanics
  • Hyperspectral Imagery
  • Laser Spectroscopy
  • Life Cycles
  • Low Earth Orbits
  • Materials
  • Microelectromechanical Systems
  • Test And Evaluation

Fields of Study

  • Materials science

Readers

  • Electrical Engineering
  • Surface Engineering/Surface Coating Technology.
  • Systems Analysis and Design

Technology Areas

  • Space