Nature and Formation of PAH and PCB Bound-Residues in the Humin Fraction of Harbor Sediments

Abstract

The lipid fraction of harbor sediment organic matter is found to be a significant control on the binding of PAHs. In the absence of lipids, binding is more nonlinear and the binding domain can be characterized as an "immobile" chemical environment from the PAH's perspective. Additional experiments with authentic polymers raise questions about the applicabilty of dual-mode sorption model to natural organic matter.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 2003
Accession Number
ADA418037

Entities

People

  • James A. Rice

Organizations

  • South Dakota State University

Tags

DTIC Thesaurus Topics

  • Aromatic Hydrocarbons
  • Aromatic Polycyclic Hydrocarbons
  • Chemical Synthesis
  • Chemistry
  • Cyclic Hydrocarbons
  • Dual Mode
  • Ecology
  • Environment
  • Humic Acid
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Isotherms
  • Organic Chemistry
  • Organic Compounds
  • Sediments
  • Sorption
  • Spectra

Readers

  • Agricultural Chemistry/Soil Science
  • Molecular and Cellular Biochemistry