Chemical Factors Associated with Environmental Assisted Cracking of Generic Gun Systems

Abstract

In the last five years, environmental assisted cracking (EAC) has re-surfaced as a service life limiting factor for some gun system designs. In these EAC affected system designs, mechanical loading factors alone do not appear to explain this loss of service life and chemical factors are implicated. Using standard interior ballistic and non-ideal gas-wall thermochemical analyses, the effect of EAC chemical factors is evaluated for three diversely different generic gun systems encompassing the spectrum of gun system types. This analysis indicates that hydrogen assisted cracking is the type of EAC responsible for this service life limitation. The results indicate that these hydrogen producing and embrittling chemical factors include: a major effect due to the addition of lubricants, a minor effect due to pressure oscillations, a subtle effect due to gaseous water-wall reactions, another subtle effect due to wall material choice, and nearly no effect due to gaseous acid-wall reactions.

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Document Details

Document Type
Technical Report
Publication Date
Jul 03, 1996
Accession Number
ADA420112

Entities

People

  • Peter O'hara
  • Samuel Sopok

Tags

DTIC Thesaurus Topics

  • Aeronautics
  • Astronautics
  • Chemical Kinetics
  • Chemical Reactions
  • Combustion
  • Combustion Products
  • D Band
  • Dielectric Gases
  • Gases
  • Liquid Propellants
  • Materials
  • Mechanical Properties
  • Propellants
  • Reaction Mechanisms
  • Solid Propellants
  • Surface Properties
  • United States

Readers

  • Life Cycle Cost Analysis
  • Systems Analysis and Design
  • ballistics.