Processing, Microstructures, and Properties of Nb-Based Metal/Silicide Alloys

Abstract

The Nb-Ti-Cr-Si-X alloys (X-Ht, Al, Sn, Fe, Ge) consisting of the solid solution Nb phase (Nb,s) in equilibrium with intermetallic phases ((NbTi)5Si3 and Cr2Nb) are potential candidates as hot-section materials for jet engines. The processing-microstructure-mechanical property relationship and damage/fracture mechanisms of these alloys have been investigated. Processing methods have included induction skull melting, rapidly solidified powder production by rotating electrode and gas-atomization processes, and thermomechanical processing involving hipping and hot-extrusions. Tensile, compressive, and toughness properties have been determined from room temperature to 1100 C in laboratory air atmosphere. The alloys exhibited a brittle-to-ductile transition at temperatures above 800 C. Below this temperature, premature brittle tensile failure was caused by large silicide agglomerates at fracture stress values <390 MPa. At 1000 C, the yield strengths, depending upon composition, ranged from 185 to 372 MPa, while at 1100 C, they ranged from 138 to 219 MPa. The toughness values ranged from ^10 - 17 MPavm from room temperature to 1100 C.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2003
Accession Number
ADA420752

Entities

People

  • Madan G. Mendiratta

Organizations

  • Universal Energy Systems

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Alloys
  • Atomization
  • Chemical Analysis
  • Chemistry
  • Failure Mode And Effect Analysis
  • Materials
  • Mechanical Properties
  • Mechanics
  • Oxidation Resistance
  • Resistance
  • Solid Solutions
  • Toughness
  • Transition Temperature
  • Turbines
  • Yield Strength

Fields of Study

  • Materials science

Readers

  • Materials Science (Mechanical Engineering).
  • Powder metallurgy of Titanium alloys.