Polymers and Oligomers of Carbon-Sulfur Helicenes

Abstract

Synthetic approaches to racemic and enantiomerically pure helical oligomers (helicenes)were developed. The molecular shape of the oligomers were modified with substituents to control the solid state packing; one of such oligomers was found to form a nearly isotropic chiral molecular glass with a significant rotatory power.

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Document Details

Document Type
Technical Report
Publication Date
Mar 23, 2004
Accession Number
ADA421423

Entities

People

  • Andrzej Rajca

Organizations

  • University of Nebraska-Lincoln Department of Chemistry

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Couplings
  • Crystals
  • Department Of Defense
  • Diseases And Disorders
  • Electro-Optical Sensors
  • Films
  • Helium Neon Lasers
  • Information Operations
  • Materials
  • Molecules
  • Oligomers
  • Optical Waveguides
  • Organic Materials
  • Shape
  • Thin Films
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology
  • Structural Dynamics.