Polynitrogen Chemistry: Recent Development in Pentazole and Polyazide Chemistry

Abstract

Partial contents: Polynitrogen Chemistry: Recent Development in Pentazole and Polyazide Chemistry, Why Polynitrogen Compounds?, Geometry of the N5+ cation , (In) Compatabillty of N5+, New Polynitrogen Anions as Counterparts for N5+, Synthetic Challenge How do we make These New Anions??, Formation and Stabillty of Sllyl Diazonium Salts, Synthesis of Aryldiazonium Salts, Pentazole Formation.. Not a Trivial Chore!!!, Identification of Arylpentazoles, Cleavage of the Aryl-Pentazole Bond with Retention of the Pentazole Ring, MSMS of the Parent Ion Peak, Chemical Cleavage of the C-N Bond, Aryl-pentazole bond cleavage: N5 anion in Solution, Subsequent Decomposition of the Pentazole Anion, Pentazoles with Heterocyclic Substituents, 15N NMR of 2-pentazoly!-4, 5-dicyano- imidazole, Pentazolate Anion in Solution?, Chronology of the Pentazolate Anion, What are "normal" N-N distances in azides?, Abnormalities in azide distances: Artifacts or Structural Contaminants?, Reactivity of hexachioroantimonate (VI) - with Trimethylsilylazide, The tetraphenylarsonium antimonychioride azide case.

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Document Details

Document Type
Technical Report
Publication Date
Mar 24, 2004
Accession Number
ADA422509

Entities

People

  • Ashwani Vij
  • Karl O. Christe
  • R. Haiges
  • Vandan Vij

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Chemistry
  • Chlorides
  • Crystal Structure
  • Decomposition
  • Department Of Defense
  • Detection
  • Gas Evolution
  • Heat Of Activation
  • Information Operations
  • Ionization
  • Low Temperature
  • Mass Spectrometry
  • Military Research
  • Spectra
  • Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Quantum Chemistry
  • Theoretical Analysis.