Spectrally Analyzed Embedded Infrared Fiber Optic Diagnostic of Advanced Composite Propellant Combustion

Abstract

This is the final report for a program to extend an embedded-infrared-fiber propellant strand burning diagnostic by replacing bandpass filter detection by spectral detection. This work builds on previous investigations into the chemical and physical processes occurring in the condensed phases of nitramine advanced composite propellants, in which we observed decomposition product gases by infrared absorption in a small volume below the flame front. Detection of infrared absorption spectra along with video camera and embedded thermocouple records allows characterization of the evolution of decomposition regions by correlating time, spatial location, temperature and decomposition species fractions. Much of the effort of the program went into optimizing the sensitivity of the FTIR spectrometer/fiber optic apparatus, and into constructing test articles. The difficulty of these tasks limited us to only a handful of successful burns. The spectra obtained clearly show N2O and CO2, thus confirming our earlier work and adding a new species to those detected previously. Evidence for other gases is less certain.

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Document Details

Document Type
Technical Report
Publication Date
Mar 31, 2003
Accession Number
ADA422571

Entities

People

  • Joda Wormhoudt

Organizations

  • Aerodyne Research

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Burning Rate
  • Chemistry
  • Combustion
  • Composite Materials
  • Composite Propellants
  • Computer Programs
  • Data Acquisition
  • Decomposition
  • Detection
  • Energetic Materials
  • Military Research
  • Propellants
  • Solid Propellants
  • Spectra
  • Spectrometers

Fields of Study

  • Physics

Readers

  • Astronomy/Astrophysics
  • Organic Chemistry
  • Rocket Propulsion.