Organic Isothiocyanates: Dietary Modulators of Doxorubicin Resistance in Breast Cancer

Abstract

Drug resistance is the main cause for therapeutic failure and death in breast cancer. Our goal is to evaluate dietary organic isothiocyanates (ITCs) as inhibitors of MDR. Our studies have demonstrated that phenethyl ITC (PEITC), benzyl ITC (BITC) and naphthyl ITC (NITC) can inhibit P-glycoprotein-mediated efflux in cell lines that overexpress P-gp, as well as in cell lines that overexpress another MDR protein, Multidrug Resistance-associated protein (MRP1). Studies evaluating the mechanism of this interaction have suggested that PEITC is an inhibitor, but not a substrate for P-gp. ITCs inhibit MRP1 through binding interactions, as well as the depletion of the cofactor for transport, glutathione. HPLC assays have been developed to determine the concentrations of these ITCs in biological samples, and a novel LC/MS/MS assay developed for PEITC, in order to obtain the needed specificity and sensitivity for in vivo studies. The stability and pharmacokinetics of NITC and PEITC have been determined. Both NITC and PEITC exhibit dose-dependent disposition, with clearance decreasing with increasing dose. The bioavailability of PEITC was determined for the first time, and found to be excellent (>80%). The ITCs may represent a new class of inhibitors of MDR in breast cancer.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2003
Accession Number
ADA424671

Entities

People

  • Marilyn E. Morris

Organizations

  • State University of New York

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DTIC Thesaurus Topics

  • Brain
  • Cells
  • Chemical Synthesis
  • Chemistry
  • Drug Abuse
  • Health Services
  • Mass Spectrometry
  • Medical Personnel
  • Organic Chemistry
  • Pharmacies

Fields of Study

  • Chemistry
  • Medicine

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  • Cellular and Molecular Pathways of Apoptosis.
  • Oncology (Cancer Research).
  • Prostate Cancer Biology.

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