Breathability and Selectivity of Selected Materials for Protective Clothing

Abstract

A series of materials was evaluated for its potential use as breathable (high water transport) barriers (low chemical agent transport) for military and civilian protective clothing apparel. The vapor transmission rates and effective permeabilities of water and dimethyl methyl phosphonate (DMMP) simulant for chemical agent (Sarin) through commercial and experimental polymeric membranes were measured using a modified American Society for Testing and Materials Method E-96-95. A variety of different materials from different companies was examined; unfortunately, some cannot be named due to proprietary restrictions. Materials examined included expanded PTFE, Nafion 117, sulfonated polystyrene-polyethylene-ran-polybutylene-polystyrene, sulfonated polystyrenepolyisobutylene-polystyrene, as well as four experimental and commercial membranes (A, B, C, and D). Results demonstrated that laminated membrane A had the highest breathability (effective permeability of water vapor); however, an experimental laminated material C possessed the highest selectivity with sufficient breathability, where selectivity was defined as the ratio of water permeability to DMMP permeability. Based on the results from this study, material C presented the greatest potential for a breathable barrier material for a chemical protective clothing application.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2004
Accession Number
ADA425206

Entities

People

  • Eugene G. Napadensky
  • Yossef A Elabd

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Human Systems

DTIC Thesaurus Topics

  • Alkenes
  • Biomedical And Dental Materials
  • Body Weight
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Clothing
  • Fabrics
  • Films
  • Laminates
  • Liquid Chromatography
  • Permeability
  • Physical Properties
  • Polymeric Films
  • Polymers
  • Protective Clothing
  • Water Vapor

Fields of Study

  • Materials science

Readers

  • Analytical Chemistry
  • Molecular and Cellular Biochemistry
  • Surface Coatings Technology.