Investigation of Ultrafast Condensed Phase Reactions Between Nanopowders

Abstract

The specific research objectives of this grant were on mathematical modeling of ultrafast condensed phase reactions with and without pressure gradients generated by the reaction and on investigation of combustion characteristics of reacting systems consisting of nanopowders. One-dimensional mathematical models were derived and solved numerically. These models predict qualitatively combustion from propagation in such reacting systems. It was also found that surface functionalization of aluminum nanopowders significantly slows down its reaction with moisture. It was demonstrated experimentally that coated aluminum nanopowders with oleic acid or silanes react even better with copper, molybdenum, and tungsten oxides. This interesting discovery can be explained by more ultimate mixing of heterogeneous reactants. In addition, results on characterization of nanopowders and mixing of nanoreactants are presented as well.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 2004
Accession Number
ADA425387

Entities

People

  • Jan A. Puszynski

Organizations

  • South Dakota School of Mines and Technology

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Aluminum Oxides
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Energetic Materials
  • Ignition Lag
  • Materials
  • Materials Science
  • Mathematical Models
  • Measurement
  • Metal Oxides
  • Metals
  • Metastable Intermolecular Composites
  • Nanoparticles
  • Nanotechnology
  • Oleic Acid
  • Oxides

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Military Logistics and Supply Chain Management
  • Surface Engineering/Surface Coating Technology.