Thermal and Electrochemical Models for Batteries During High Rates of Discharge

Abstract

The first of the three pans of this work documents the effort toward the original objective of the grant: understanding how commercial software could be modified to understand the three dimensional thermal and electrochemical gradients in a silver/zinc battery during high rates of discharge. This objective had broad applications for accelerated design of new batteries if we could use the mathematical solvers in commercial software packages because these software packages have automatic grid generation procedures. Unfortunately the state of the an of those software packages in 2000 required extensive custom modification and we concluded that the complex models of battery required too much computation time to be useful for transient behavior of the Ag/Zn system. The second pan documents where an understanding of the 3-D transient behavior can be obtained with commercial software modified to account for the electrochemistry. The third pan of this report documents the experimental work on transient behavior of fuel cells. In this third pan, we were able to demonstrate how complete 3-D models may lead to improved design and operation.

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Document Details

Document Type
Technical Report
Publication Date
Aug 15, 2004
Accession Number
ADA426354

Entities

People

  • John W. Van Zee

Organizations

  • University of South Carolina

Tags

Communities of Interest

  • Energy and Power Technologies
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Boltzmann Equation
  • Chemical Engineering
  • Chemical Reactions
  • Chemistry
  • Composite Materials
  • Computational Fluid Dynamics
  • Computational Science
  • Computations
  • Computer Programs
  • Electrochemical Reactions
  • Electrochemistry
  • Fluid Dynamics
  • Fluid Flow
  • Heat Transfer
  • Pressure Distribution
  • Three Dimensional
  • Two Dimensional

Readers

  • Battery Technology and Engineering
  • Computational Fluid Dynamics (CFD)
  • Computer Science.

Technology Areas

  • Biotechnology