Interfacial Polymerization of Polyaniline Nanofibers Grafted to Au Surfaces

Abstract

In this work, polyaniline/poly(sulfonated styrene) nanofiber composites were prepared by an interfacial method. The in-situ polymerization technique of these PANI nanofibers in the presence of sulfonated polystyrene allowed for the growth of PANI 2-D nanostructures embedded in the polymerized sulfonated host. This facile approach enables a self-assembly of these nanofibers into a workable, robust, conductive composite that can be processed and cast from water. A low accelerating voltage SEM was used to image these twisted fibers within the bulk of the cast film. In addition, the SEM confirmed the self-assembly of these 40-50 nm fibers within the host PSS to yield an electrically conducting composite film.

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Document Details

Document Type
Technical Report
Publication Date
Aug 10, 2004
Accession Number
ADA426600

Entities

People

  • A. R. Hopkins
  • D. D. Sawall
  • R. A. Lipeles
  • R. M. Villahermosa

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Conductive Polymers
  • Corporations
  • Electron Microscopes
  • Fabrication
  • Fibers
  • Materials
  • Materials Laboratories
  • Materials Processing
  • Monomolecular Films
  • Nanofibers
  • Nanomaterials
  • Polyanilines
  • Polymerization
  • Self Assembled Monolayers
  • Two Dimensional

Fields of Study

  • Materials science

Readers

  • Nanocomposite Materials Science
  • Polymer Science and Technology

Technology Areas

  • Biotechnology
  • Microelectronics