Novel Protein-Protein Interactions of the Yersinia pestis Type III Secretion System Elucidated With a Matrix Analysis by Surface Plasmon Resonance and Mass Spectrometry

Abstract

Binary complexes formed by components of the Yersinia pestis type III secretion system were investigated by surface-plasmon resonance (SPR) and matrix-assisted laser desorption time-of-flight (MALDI-TOF) mass spectrometry. Pair-wise interactions between fifteen recombinant Yersinia outer proteins (Yops), regulators and chaperones were first identified by SPR. Mass spectrometry confirmed over 80% of the protein-protein interactions suggested by SPR, and new binding partners were further characterized. The Yop secretion protein (Ysc) M2 of Y. enterocolitica and LcrQ of Y. pestis, formerly described as ligands only for the specific Yop chaperone (Syc) H, formed stable complexes with SycE. Additional previously unreported complexes of YscE with the translocation-regulator protein TyeA and the thermal-regulator protein YmoA, and multiple potential protein contacts by YscE, YopK, YopH, and LcrH were also identified. Because only stably folded proteins were examined, the interactions we identified are likely to occur either before or after transfer through the injectosome to mammalian host cells, and may have relevance to understanding disease processes initiated by the plague bacterium.

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Document Details

Document Type
Technical Report
Publication Date
Sep 10, 2004
Accession Number
ADA426987

Entities

People

  • Ernst Brueggemann
  • Harry Hines
  • Joseph E. Tropea
  • Kari Holman
  • Sarah O'brien
  • Wieslaw Swietnicki!

Organizations

  • National Cancer Institute

Tags

DTIC Thesaurus Topics

  • Amino Acids
  • Cells
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Mass Spectra
  • Mass Spectrometry
  • Plasmons
  • Polymerase Chain Reaction
  • Protein-Protein Interactions
  • Regulators
  • Resonance
  • Secretion
  • Spectrometry
  • Surface Plasmon Resonance
  • Surface Plasmons
  • Three Dimensional

Fields of Study

  • Chemistry

Readers

  • Microbial Pathology
  • Molecular Photonics/Laser Physics
  • Molecular and Cellular Biochemistry

Technology Areas

  • Directed Energy