NMR Studies of Polymer Nanocomposites

Abstract

Methods developed and refined to characterize ion and molecular transport process in disordered media are described. The primary tool is pulsed field gradient NMR. A static field gradient method was developed which makes possible variable pressure diffusion measurement, and the application to the important fuel cell membrane NAFION constitute the first results of their kind ever published. Standard ambient pressure results for lithium ion conducting polymer electrolytes containing nanoscopic silica are included, as well as the description of a novel scheme to produce highly conducting polymer electrolytes by magnetic field alignment of the polymer chains. Fuel cell membranes developed by collaborators at Wright-Patterson Air Force Base were also investigated.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2001
Accession Number
ADA428869

Entities

People

  • Steve G. Greenbaum

Organizations

  • Hunter College

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies
  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Cells
  • Chemistry
  • Diffusion
  • Diffusion Coefficient
  • Electrolytes
  • Films
  • Fuel Cells
  • High Pressure
  • Magnetic Fields
  • Materials
  • Materials Processing
  • Materials Science
  • Measurement
  • Membranes
  • Nanocomposites
  • Physical Chemistry
  • Polymer-Matrix Nanocomposites

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Nanoscale Plasmonic Nanotechnology
  • Plasma Physics / Magnetohydrodynamics

Technology Areas

  • Biotechnology