JP-8 Catalytic Cracking for Compact Fuel Processors

Abstract

In processing heavier hydrocarbons such as military logistic fuels (JP-4, JP-5, JP-8 and JP-100), kerosene, and diesel to produce hydrogen for fuel cell use, several issues arise. First, these fuels have high sulfur content, which can poison and deactivate components of the reforming process and the fuel cell stack; second, these fuels may contain non-volatile residue (NVR), up to 1.5 vol. %, which could potentially accumulate in a fuel processor; and third is the high coking potential of heavy hydrocarbons. Catalytic cracking of a distillate fuel prior to reforming can resolve these issues. Cracking using an appropriate catalyst can convert the various heavy organosulfur species in the fuel to lighter sulfur species such as hydrogen sulfide (H2S), facilitating subsequent sulfur adsorption on zinc oxide (ZnO). Cracking followed by separation of light cracked gas from heavies effectively eliminates non-volatile aromatic species. ... Cracking conversion results, as well as sulfur and hydrocarbon distribution in the light cracked gas, are presented for the two catalysts to provide a performance comparison.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2004
Accession Number
ADA429166

Entities

People

  • Aly H. Shaaban
  • Franklin H. Holcomb
  • Michael J. Binder
  • Reza Salavani
  • Timothy J. Campbell

Organizations

  • Air Force Research Laboratory

Tags

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Alkenes
  • Catalysts
  • Catalytic Cracking
  • Cells
  • Chemical Reactions
  • Conversion
  • Fuel Cells
  • Heat Transfer
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Hydrogen
  • Hydrogen Sulfides
  • Molecular Weight
  • Power Supplies
  • Solid Oxide Fuel Cells
  • Sulfur Compounds

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Petroleum Engineering

Technology Areas

  • Biotechnology