Molecular Beam Studies of Reactions Between Warfare Agents Simulants and Solid Surfaces

Abstract

Our experimental studies are directed at elucidating the mechanisms of interfacial adsorption, desorption, and reactions in collisions between chemical warfare simulants and solid surfaces. The investigations are facilitated by using molecular beam scattering from well characterized, MgO surfaces and model self-assembled monolayer or multilayer surfaces. Much of our efforts for this funding period have been focused on constructing a state-of-the-art ultrahigh vacuum gas-dosing instrument, synthesizing new MgO nano-structured materials, and exploring uptake in new silicon-oxide thin films. The instrument is now complete and enabling us to measure gas-surface reaction probabilities and branching ratios, determine surface adsorbate concentrations and structures, and measure the residence times and bonding energies of molecules on or within a material.

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Document Details

Document Type
Technical Report
Publication Date
Oct 27, 2004
Accession Number
ADA429646

Entities

People

  • John R Morris

Organizations

  • Virginia Tech

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Films
  • Materials
  • Materials Science
  • Measurement
  • Metal Oxides
  • Molecular Beams
  • Monomolecular Films
  • Organophosphorus Compounds
  • Self Assembled Monolayers
  • Spectra
  • Spectroscopy
  • Surface Chemistry
  • Surface Reactions
  • Ultrahigh Vacuum

Fields of Study

  • Physics

Readers

  • Critical Infrastructure Protection in CBRN and WMD Threats.
  • Molecular Photonics/Laser Physics
  • Thin Film Deposition Science.