Development of a Comprehensive and Predictive Reaction Mechanism of Liquid Hydrocarbon Fuel Combustion

Abstract

Studies were conducted to finalize a fundamental and predictive reaction model for the combustion of hydrogen and carbon monoxide through a multi-parameter optimization. These studies showed that reliable data of hydrogen and carbon monoxide oxidation at high temperatures can be reconciled be a single kinetic model. An advanced approach to solve the master equation of collision energy transfer was developed to predict the rate constants of combustion reactions of arbitrary complexities. Studies were also conducted on a class of unique combustion reactions that involve spin state crossing-one of the last few unresolved theoretical problems in combustion reaction kinetics.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Dec 15, 2004
Accession Number
ADA430011

Entities

People

  • Hai Wang

Organizations

  • University of Delaware

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Carbon Monoxide
  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Collisions
  • Combustion
  • Dielectric Gases
  • Energy
  • Energy Transfer
  • Gases
  • Hydrocarbon Fuels
  • Ignition Lag
  • Kinetics
  • Oxidation
  • Reaction Mechanisms
  • Spin States

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Computational Modeling and Simulation