Dissociation of Hexavalent Chromium from Primer Paint Particles into Simulated Mucus Fluid

Abstract

The military relies heavily on chromate primer paints to protect equipment from corrosion. Epidemiological studies link chromate exposure to cancer however limited studies suggest exposure to chromate paint particles does not increase the risk of lung cancer. The particle size and paint type may hinder chromate released into lung fluid. To simulate particle deposition in the mucosal layer of the lungs, a viable cascade impactor collected paint particles into porcine-based simulated lung fluid (SLF). Samples were tested after 24 hours for dissolved and total chromate to determine the fraction of Cr(exp +6)(exp +6) that dissociated from the particles into the Porcine-SLF. In strontium chromate paints, 0.65-2.1 microns sized particles released significantly less chromate than 2.1-7.0 micron sizes. Barium chromate paints only released 3-7% of its chromate, while strontium based paints released from 20-90%. This method demonstrates a technique to evaluate the bioavailability of contaminants from any type of aerosols.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2005
Accession Number
ADA435789

Entities

People

  • Michael P. Moran
  • Peter T. Lapuma

Organizations

  • Uniformed Services University of the Health Sciences

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Acids
  • Air Force
  • Aircrafts
  • Biomedical And Dental Materials
  • Buffers (Chemistry)
  • Cells
  • Chemistry
  • Chromium Compounds
  • Department Of Defense
  • Materials
  • Medical Personnel
  • Military Aircraft
  • Occupational Safety And Health
  • Particle Size
  • Polymeric Films
  • Resins
  • Spray Guns

Fields of Study

  • Environmental science

Readers

  • Aerosol Science/Aerosol Physics
  • Immunology and Pathology
  • Surface Coatings Technology.