Microwave Induced Reaction of H-Dimethylphosphonate With Styrene Oxide

Abstract

The reaction of a neat mixture of styrene oxide and H-dimethyl-phosphonate under microwave catalysis and without any solvent for six minutes furnished a complex mixture containing dimethyl methylphosphonate, trimethylphosphate, phenylacetaldehyde, 1-methoxy-2- phenylethanol, 1-phenylethleneglycol, cis- and trans-1, 3-diphenylcyclobutanes, hydrogen 1-(2- phenylethyl)methylphosphinate, (1-phenylethyl)dimethylphosphonate and (1-phenylethyl)- dimethylphosphonate via free radical processes. The mechanism of formation of the said compounds and their GC-MS characterization are described herein.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2002
Accession Number
ADA436045

Entities

People

  • D. K. Rohrbaugh
  • F. R. Longo
  • G. W. Wagner
  • H. Dupont Durst
  • S. Munavalli

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Advanced Electronics
  • Counter WMD

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Reactants
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Complex Mixtures
  • Energy
  • Free Radicals
  • Hydrogen
  • Mass Spectrometry
  • Methylphosphonates
  • Organic Chemistry
  • Phosphonates
  • Phosphorus
  • Phosphorus Compounds

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Organic Chemistry