Synthesis and Characterization of a New Genre of CS-Compounds

Abstract

Three groups of organic compounds are currently being used as riot control and crowd management agents. Included in these three groups are: omega-chloroacetophenones (CN), benzylidene malononitriles (CS) and dibenzo-oxazepines (OR) (Fig. 1). o-Chlorobenzylidene malononitrile (1) is the most popularly used non-lethal agent in riot control situations and military exercises. Since this compound contains chlorine, it is not environmentally safe. With a view to improve its properties and enhance its effectiveness, a new group of CS compounds containing fluorine have been synthesized using microwave exposure and new inorganic catalysts in neat reactions. The synthesis and characteristics of a novel group of CS compounds are described herein.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2002
Accession Number
ADA436073

Entities

People

  • Brenna A. Black
  • D. K. Rohrbaugh
  • F. R. Longo
  • G. W. Wagner
  • H. Dupont Durst
  • S. Munavalli

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Counter WMD

DTIC Thesaurus Topics

  • Abstracts
  • Catalysts
  • Chemical Warfare Agents
  • Chemical Weapons
  • Electron Energy
  • Elements
  • Fluorine
  • Imines
  • Incapacitating Agents
  • Incapacitation
  • Mass Spectra
  • Melting Point
  • Nonlethal Agents
  • Nonlethal Weapons
  • Organic Compounds
  • Phosgene
  • Vapor Pressure

Fields of Study

  • Chemistry

Readers

  • Educational Psychology
  • Neurotoxicology
  • Organic Chemistry