Investigation of Soman Adducts of Human Hemoglobin by Liquid Chromatography

Abstract

Verification of exposure to chemical agents is a requirement of the intelligence, depot, and demilitarization communities to confirm claims of exposure to chemical warfare agents. Improving current analytical methods and developing novel methods to verify chemical agent exposure are vital, considering the increased threat of chemical agent use and therefore the possibility of large numbers and types of biomedical samples that a relatively small number of labs must analyze. The current study focuses on development of an analytical method to determine past exposure to soman (GD) by identifying GD adducts of human hemoglobin (Hb). Although previous studies have indicated that GD does bind to the tyrosine residue in human albumin, no such adduct was found for GD and human hemoglobin.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 2004
Accession Number
ADA443087

Entities

People

  • B. A. Logue
  • B. J. Pieper
  • S. D. Royster-cunningham

Organizations

  • United States Army Medical Research Institute of Chemical Defense

Tags

DTIC Thesaurus Topics

  • Albumins
  • Amino Acids
  • Blood
  • Blood Cells
  • Blood Proteins
  • Chemical Synthesis
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Chromatography
  • Detectors
  • Hemoglobin
  • Liquid Chromatography
  • Mass Spectrometry
  • Nerve Agents
  • Spectrometry
  • Warfare

Readers

  • Analytical Chemistry
  • Computational Modeling and Simulation
  • Molecular and Cellular Biochemistry

Technology Areas

  • Biotechnology