Improved Chemical Protective Gloves Using Elastomeric Nanocomposites

Abstract

Nanocomposite Coatings of neoprene and nitrile Rubber based on InMat's environmentally friendly, water based, Nanolok coating technology have been developed. In this report, we discuss the optimization and scale up of these coating formulations that are targeted for use in multilayer chemical protective gloves. Such gloves will provide the protection of butyl based gloves while having significantly improved resistance to petroleum oils and gasoline while also being less flammable. There is also the potential for making these gloves significantly thinner than the currently used butyl rubber gloves. This report also discusses the details of permeation through multilayer structures, and shows how to model both the steady state permeation rate and the kinetics. It is the short time kinetics after initial exposure to a chemical warfare agent (CWA) that is critical to determining the protection. The modeling work described here is used to demonstrate that the use of nanocomposite barrier layers in a multilayer structure provide some surprisingly important dependence on the details of how the barrier is deployed in the structure. This work has led to a patent application, and has been verified using detailed studies of the kinetics of helium permeation. Initial work on solvents and CWA simulants is also presented to further demonstrate the potential of this multilayer approach.

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Document Details

Document Type
Technical Report
Publication Date
Feb 06, 2006
Accession Number
ADA443599

Entities

People

  • Carrie A. Feeney
  • Harris A. Goldberg

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Aspect Ratio
  • Barrier Coatings
  • Butyl Rubber
  • Chemical Warfare
  • Chemical Warfare Agents
  • Composite Materials
  • Equations
  • Materials
  • Materials Laboratories
  • Materials Testing
  • Measurement
  • Nanocomposites
  • Natural Rubber
  • Polymeric Films
  • Polymers
  • Test And Evaluation

Fields of Study

  • Materials science

Readers

  • Materials Science
  • Surface Coatings Technology.
  • Thin Film Deposition Science.