Direct Simulation of Ultrafast Detonations in Mixtures

Abstract

nearly a century experimental measurements of the velocities of detonations in gases have been found in general agreement with those of the Chapman-Jouguet (C-J) hypothesis predicting velocities, relative to the burned gases, equal to the speed of sound in the burned gases. This was further supported by the Zeldovich - von Neumann - D ring (ZND) theories predicting Chapman-Jouguet velocities for detonations in which the shock and reaction zones are separated. However, for a very fast reaction, the shock and reaction regions overlap and the assumptions required for the C-J and ZND theories are no longer valid. Previous work with the direct simulation method established conditions for forcing the reaction and shock regions to coalesce in a detonation wave by means of a very fast exothermic reaction. The resulting detonation velocities were characterized as ultrafast, as they were found to exceed the steady-state velocities predicted by the C-J and ZND theories. Continued investigation into the ultrafast regime has allowed for the further development of this inconsistency with theory by including a heavy non-reacting gas in the mixture. The resulting gaseous mixtures closely followed the C-J predicted behavior for slow reactions, and for very fast reactions were found to produce ultrafast detonations with a substantially greater deviation from C-J behavior.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jul 13, 2005
Accession Number
ADA446019

Entities

People

  • James B. Anderson
  • Lyle N. Long
  • Patrick D. O'connor

Organizations

  • Pennsylvania State University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Reaction Properties
  • Chemical Reactions
  • Complex Systems
  • Detonation Waves
  • Detonations
  • Energy
  • Equations
  • Exothermic Reactions
  • Gas Dynamics
  • Gases
  • Heat Of Activation
  • High Temperature
  • Particles
  • Reactive Gases
  • Simulations
  • Waves

Fields of Study

  • Physics

Readers

  • Combustion Dynamics and Shock Wave Physics.
  • Combustion science or combustion engineering.
  • Computational Modeling and Simulation