Potassium Ferrate: A Novel Chemical Warfare Agent Decontaminant

Abstract

Chemical warfare agents (CWAs) present a potential threat to military and civilian populations. Current decontamination formulations for CWAs, however, have several shortfalls, including environmental hazards, health hazards, practical use limitations, logistical management difficulties, and/or unsatisfactory CWA destruction efficiencies. Potassium ferrate (K2FeO4) addresses all of these issues through its high oxidation potential, stable shelf life, and benign reduced state, namely iron oxide. A series of bench-scale trials on surrogate and actual CWAs demonstrated the potential efficacy of K2FeO4 as a viable decontamination agent. Destruction efficiencies using paste and aqueous K2FeO4 formulations exceeded 99% for 2,2-dichloroethyl ether, Sarin, Soman, mustard and V-nerve agents. The reaction times were as good as or better than commonly accepted decontaminants, such as bleach and sodium hydroxide.

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Document Details

Document Type
Technical Report
Publication Date
Nov 16, 2004
Accession Number
ADA449526

Entities

People

  • Bruce Monzyk
  • F. M. Von Fahnestock
  • Russell Greene

Organizations

  • Battelle Memorial Institute

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Abstracts
  • Buffers (Chemistry)
  • Chemical Warfare
  • Chemical Warfare Agents
  • Civilian Population
  • Decontamination
  • Efficiency
  • Hydroxides
  • Iron Oxides
  • Materials
  • Nerve Agents
  • Oxidation
  • Potassium
  • Reaction Time
  • Shelf Life
  • Sodium Hydroxide
  • Warfare

Readers

  • Analytical Chemistry
  • Materials Science
  • Systems Analysis and Design