Uniform Droplet Deposition of Thickened Chemical Agent Simulants By Supercritical Carbon Dioxide Viscosity Reduction

Abstract

Study of the fate of chemicals on substrates requires that those chemicals be applied to the substrate in a uniform and reproducible manner. Relatively simple means of droplet deposition of non-viscous chemicals are satisfactory, however thickened chemicals present problems using the same deposition techniques. By using supercritical carbon dioxide as a diluent, we were able to reduce the viscosity of various polymer-thickened chemicals and store them in a high-pressure reservoir. We achieved up to 20 fold reductions in viscosity of polymer-chemical mixtures and deposit them with no residual solvent retained within the deposited material.

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Document Details

Document Type
Technical Report
Publication Date
Nov 16, 2004
Accession Number
ADA449549

Entities

People

  • Michael V. Henley
  • Richard M. Weber

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Carbon Dioxide
  • Chemical Agent Simulants
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Critical Temperature
  • Diameters
  • High Pressure
  • Materials
  • Measurement
  • Organic Compounds
  • Physical Properties
  • Spray Guns
  • Stainless Steel
  • Viscometers
  • Viscosity

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Petroleum Engineering
  • Thin Film Deposition Science.