Breath Analysis Using Photoionization Mass Spectrometry

Abstract

REMPI (Resonantly Enhanced Multi Photon Ionization) is an ultra-sensitive analytical technique based on the unique combination of laser spectroscopy and mass spectrometry that can rapidly identify and quantify vapor-phase constituents present at part per trillion levels. We have used this method to examine human breath samples for biomarkers of infection. Based on the observed results, we estimate our limit of detection for the photoionization system is a factor of 40-100 times lower than we can achieve using the newest GC/MS instrument. Of more importance perhaps, compounds such as benzene, toluene or even dichlorobenzene can readily be detected using this method.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Nov 16, 2004
Accession Number
ADA449580

Entities

People

  • Harald Oser
  • Michael J. Coggiola
  • Steve E. Young

Organizations

  • SRI International

Tags

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Detection
  • Detectors
  • Diseases And Disorders
  • Health Services
  • Ionization
  • Mass Spectrometers
  • Mass Spectrometry
  • Medical Personnel
  • Photoionization
  • Spectra
  • Spectrometers
  • Spectrometry
  • Spectroscopy
  • Volatile Organic Compounds

Fields of Study

  • Physics

Readers

  • Analytical Chemistry
  • Computational Modeling and Simulation
  • Molecular Photonics/Laser Physics

Technology Areas

  • Directed Energy