Thermochemical Properties, Reaction Paths and Kinetic Mechanism for Sulfur-Chloro Hydrocarbon Combustion: Part I: Thermochemistry and Pyrolysis of Chlorosulfides

Abstract

Almost no data exists in the literature on thermochemical properties enthalpy of formation, entropy or heat capacities for chlorinated sulfur hydrocarbons and oxygenated intermediates in atmospheric or thermal oxidation reactions. Even less kinetic data exists on the elementary processes involved in these reaction systems. This study describes a first attempt to generate a thermochemical property data set and an elementary reaction mechanism for pyrolysis and oxidation of diethyl sulfide and dichloro-diethyl sulfide.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 2003
Accession Number
ADA451431

Entities

People

  • Adel F. Sarofim
  • Christopher J. Montgomery
  • Jongwoo Lee
  • Joseph W. Bozzelli
  • Michael J. Bockelie

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemical Engineering
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Chemistry
  • Combustion
  • Computational Chemistry Methods
  • Decomposition
  • Dihedral Angle
  • Dissociation
  • Mustard Agents
  • Pyrolysis
  • Thermochemistry
  • Thermodynamic Properties

Fields of Study

  • Chemistry
  • Environmental science

Readers

  • Materials Science and Engineering.
  • Organic Chemistry