A Homogenized Energy Model for Hysteresis in Ferroelectric Materials: General Density Formulation

Abstract

In this paper, we construct a framework for modeling hysteresis and constitutive nonlinearities in ferroelectric compounds based on energy analysis at mesoscopic scales in combination with stochastic homogenization techniques to construct macroscopic models. In the first step of the development, previous analysis is used to construct Helmholtz and Gibbs energy relations at the lattice level. This provides local polarization relations which can be extrapolated to provide constitutive models for certain homogeneous, single crystal compounds. To incorporate material and field nonhomogeneities, as well as the effects of polycrystallinity, certain parameters in the local models are assumed to be manifestations of underlying distributions having densities which must be identified for a given compound. Two techniques for estimating the unknown densities are presented, and the accuracy of the resulting model is illustrated for both symmetric major loops and biased minor loops through fits and predictions with experimental PZT4 and PZT5H data.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2004
Accession Number
ADA452029

Entities

People

  • Andrew Hatch
  • Binu Mukhergee
  • Ralph C. Smith
  • Shifang Liu

Organizations

  • North Carolina State University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Accuracy
  • Algorithms
  • Computations
  • Computer Programming
  • Data Sets
  • Differential Equations
  • Domain Walls
  • Electric Fields
  • Ferroelectric Materials
  • Free Energy
  • Frequency
  • Hysteresis
  • Magnetic Materials
  • Materials
  • Quadratic Programming
  • Single Crystals
  • Transducers

Fields of Study

  • Mathematics

Readers

  • Computational Modeling and Simulation
  • Materials Science and Engineering.