Dissociation of Hexavalent Chromium from Sanded Paint Particles into a Simulated Lung Fluid

Abstract

Chromate-containing paint coatings are the primary means of protecting an aircraft surface from corrosion in the US military. Studies clearly link chromate exposure to human lung cancer. However, the few studies of the painting industry suggest that chromate exposure from paint particles does not increase the risk of lung cancer. Even fewer studies have evaluated sanding of chromate containing paint layers, and data suggests that sanders have an increased risk of lung cancer. A 6-stage cascade impactor was used to imitate particle deposition onto a layer of lung fluid. The lung fluid was simulated with a porcine based mucin. Sanded particles were collected based on particle size into the impactor's six petri dishes, which contained lung fluid. After 24 hours, the fraction of chromate that dissolved into the lung fluid generally ranged from 60-90% for strontium chromate based paints and 10-50% for barium chromate based paints. In water and solvent based strontium chromate paints, there was lifetime difference between sanded and freshly sprayed paint particles. But for polyurethane and barium chromate based paints, sanded particles dissociated significantly more chromate than paint particles.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2006
Accession Number
ADA452154

Entities

People

  • Steven H. Lange

Organizations

  • Uniformed Services University of the Health Sciences

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Aerospace Industry
  • Air Force
  • Aluminum Alloys
  • Buffers (Chemistry)
  • Chemical Synthesis
  • Chemistry
  • Chromium
  • Dissociation
  • Measurement
  • Metals
  • Mixing
  • Nebulizers And Vaporizers
  • Occupational Safety And Health
  • Particle Size
  • Particles
  • Public Health
  • Resins

Readers

  • Aerosol Science/Aerosol Physics
  • Oncology
  • Surface Coatings Technology.