Uptake and Transformation of the Propellants 2,4-DNT, Perchlorate and Nitroglycerin by Grasses

Abstract

The feasibility of using grasses, yellow nutsedge (Cyperus escalantus), Indian grass (Sorghastrum nutans) and big bluestem (Andropogon gerardii) in the clean-up of propellant contaminated soil was assessed by performing hydroponic and soil experiments. The propellants 2,4-dinitrotoluene (2,4-DNT), perchlorate and nitroglycerin (GTN) often contaminate firing ranges due to partially detonated ordnances and incomplete combustion of munitions. In hydroponic experiments, sorption of 2,4-DNT to roots was significant in the grasses. Perchlorate accumulated in large amounts in leaves of the grasses with maximum accumulation in yellow nutsedge (732 mg kg-1). GTN was removed from the solution rapidly and almost 100% degradation was seen in all grasses within 52 hours. From soil experiments, it is evident that yellow nutsedge was effective in degrading 2,4-DNT. Perchlorate was accumulated in leaves of yellow nutsedge and Indian grass and GTN degradation was nearly 100% in Indian grass. Degradation in perchlorate and OTN was by bacteria.

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Document Details

Document Type
Technical Report
Publication Date
Jul 31, 2006
Accession Number
ADA452439

Entities

People

  • Guy Riefler
  • Sushma Guruswamy
  • Victor Medina

Organizations

  • Ohio University

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Ammonium Perchlorate
  • Bacteria
  • Biodegradation
  • Chemistry
  • Chlorine Compounds
  • Control
  • Ecology
  • Environmental Health
  • Environmental Protection
  • Explosives
  • Groundwater
  • Liquid Chromatography
  • Microorganisms
  • Munitions
  • Propellants
  • Sodium Compounds

Fields of Study

  • Environmental science

Readers

  • Agricultural Chemistry/Soil Science