Vaporized Hydrogen Peroxide (VHP) Decontamination of VX, GD, and HD

Abstract

Vaporized Hydrogen Peroxide (VHP) has been utilized for more than a decade to sterilize clean rooms and pharmaceutical processing equipment and, quite recently, to decontaminate anthrax-ridden buildings. VHP is also suitable for the decontamination of VX and HD, which readily converts these agents to ethyl methylphosphonic acid and bis(2-chloroethyl) sulfoxide, respectively. However, GD is quite stable in the presence of VHP. The simple addition of low-levels of ammonia gas renders VHP reactive towards GD, converting it pinacolyl methylphosphonic acid. Thus, with suitable activation via ammonia gas, VHP affords the broad-spectrum decontamination of VX, GD, and HD. Potential decontamination applications for this gaseous reactant system include: buildings, vehicle and aircraft interiors, and sensitive equipment.

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Document Details

Document Type
Technical Report
Publication Date
Nov 19, 2003
Accession Number
ADA453108

Entities

People

  • David C. Sorrick
  • George Wayne Wagner
  • Iain F. Mcvey
  • Lawrence R. Procell
  • Lewis I. Schwartz
  • Mark D. Brickhouse
  • Zoe A. Hess

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Counter WMD

DTIC Thesaurus Topics

  • Chemical Warfare Agents
  • Chemical Weapons
  • Decontamination
  • Elements
  • Flow Rate
  • G Agents
  • Homeland Defense
  • Hydrogen
  • Nerve Agents
  • Peroxides
  • Processing Equipment
  • Reactive Gases
  • Rocket Oxidizers
  • Sulfur Compounds
  • Vehicles
  • Vesicants
  • Weapons Of Mass Destruction

Readers

  • Analytical Chemistry
  • Environmental Engineering.
  • Military/Explosive Ordnance Disposal (EOD) Technology